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2014-05

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/165281

Template arrangement of {Ni3(&m3-OH)(SO4)(R-NO)2}+ fragments around Na+ cations: An unprecedented {Ni12Na} unit linked by oximate and sulfate bridges

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https://doi.org/10.1016/j.inoche.2014.02.033

Abstract

Anovel {−Ni12Na2-Ni-}n chain has been characterized fromthe reaction between 2-pyridylcyanoxime, (pyC{CN}NOH), and nickel(II) sulfate. The template synthesis around a Na+ cation gives an unprecedented arrangement of four nickel triangles coordinated to the central sodium ion by sulfato bridges.

Subject

Química supramolecular, Propietats magnètiques, Sulfat de ferro

Subject (English)

Supramolecular chemistry, Magnetic properties, Ferrous sulfate

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Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

Citation

ESTEBAN JARNE, Jordi, FONT BARDIA, Ma. Mercedes and ESCUER FITÉ, Albert. Template arrangement of {Ni3(&m3-OH)(SO4)(R-NO)2}+ fragments around Na+ cations: An unprecedented {Ni12Na} unit linked by oximate and sulfate bridges. Inorganic Chemistry Communications. 2014. Vol. 43, num. 169-172. ISSN 1387-7003. [consulted: 20 of August of 2026]. Available at: https://hdl.handle.net/2445/165281

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