Stereoselective alkylation of (S)-N-acyl-4-isopropyl-1,3-thiazolidine-2-thiones catalyzed by (Me3P)2NiCl2

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dc.contributor.authorFernandez-Valparis, Javier
dc.contributor.authorRomo Fernández, Juan Manuel
dc.contributor.authorRomea, Pedro
dc.contributor.authorUrpí Tubella, Fèlix
dc.contributor.authorKowalski, Hubert
dc.contributor.authorFont Bardia, Ma. Mercedes
dc.date.accessioned2020-06-06T08:18:06Z
dc.date.available2020-06-06T08:18:06Z
dc.date.issued2015-07-02
dc.date.updated2020-06-06T08:18:06Z
dc.description.abstractThe structurally simple (Me3P)2NiCl2 complex catalyzes SN1-type alkylations of chiral N-acyl thiazolidinethiones with diarylmethyl methyl ethers and other stable carbenium cations. The former can contain a variety of functional groups and heteroatoms at the α-position. The resultant adducts are isolated as single diastereomers in high yields and can be converted into enantiomerically pure derivatives in a straightforward manner.
dc.format.extent16 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec653265
dc.identifier.issn1523-7060
dc.identifier.urihttps://hdl.handle.net/2445/164597
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/acs.orglett.5b01626
dc.relation.ispartofOrganic Letters, 2015, vol. 17, num. 14, p. 3540-3543
dc.relation.urihttps://doi.org/10.1021/acs.orglett.5b01626
dc.rights(c) American Chemical Society , 2015
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)
dc.subject.classificationCatàlisi asimètrica
dc.subject.classificationCompostos de níquel
dc.subject.classificationAlcohols
dc.subject.classificationÈters
dc.subject.otherEnantioselective catalysis
dc.subject.otherNickel compounds
dc.subject.otherAlcohols
dc.subject.otherEthers
dc.titleStereoselective alkylation of (S)-N-acyl-4-isopropyl-1,3-thiazolidine-2-thiones catalyzed by (Me3P)2NiCl2
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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